Polymaker PC-ABS Safety Data Sheet | SDS for High Performance 3D Printing Material

Polymaker PC-ABS Safety Data Sheet

Safety Data Sheet

1. Identification

Material Name: Polymaker™ PC-ABS

Company: JF Polymers (Suzhou) Co. Ltd

Address: Haicheng Industrial Park, Bldg 7, Changshu Economic Development Zone (CEDZ), Changshu, Jiangsu Province 215513, China

Tel/Fax: +86-512-52096516 / +86-512-52096512

Use: 3D Printing Filament

Chemical Family: Thermoplastic Polymer

2. Hazards Identification

GHS Classification

This product is not hazardous in the form in which it is shipped by the manufacturer.

GHS Label Elements

Signal word: Warning

Hazard statements: If fine particles are generated during further processing, handling, or by other means, product may form combustible dust concentrations in air.

3. Composition/Information on Ingredients

There are no hazardous components above the relevant concentration limits according to OSHA HazCom 2012.

4. First Aid Measures

Most Important Symptoms/Effects

Acute: Contact with heated material can cause thermal burns. Gases and fumes evolved during the thermal processing or decomposition of this material may irritate the eyes, skin, or respiratory tract.

Eye Contact

In case of contact, flush eyes with plenty of lukewarm water.

Skin Contact

Cool melted product on skin with plenty of water. Do not remove solidified product. Get medical attention if thermal burn occurs.

Inhalation

Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.

Ingestion

Get medical attention.

5. Firefighting Measures

Suitable Extinguishing Media

Water fog, Dry chemical, Carbon dioxide (CO2), Foam

Unsuitable Extinguishing Media

High Pressure Water Streams

Fire Fighting Procedure

Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes.

Hazardous Decomposition Products

By Fire and Thermal Decomposition: Phenol; Styrene; Acrylonitrile Carbon oxides, Hazardous decomposition products due to incomplete combustion

Unusual Fire/Explosion Hazards

Toxic and irritating gases/fumes may be given off during burning or thermal decomposition. Avoid generating dust: fine dust dispersed in air in sufficient concentrations and in the presence of an ignition source is a potential dust explosion hazard.

6. Accidental Release Measures

Spill and Leak Procedures

If molten, allow material to cool and place into an appropriate marked container for disposal. Sweep up and shovel into suitable containers for disposal. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture as they are released into the atmosphere in sufficient concentrations. Avoid dispersal of dust in the air (e.g., cleaning dust from surfaces with compressed air).

7. Handling and Storage

Handling/Storage Precautions

Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling. Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dust does not accumulate on surfaces. Solid particulate can generate electrical charging during operations such as unloading from containers and pneumatic transfer. Provide adequate precautions, such as electrical grounding and bonding, where conductive equipment is involved.

Storage Period

None.

Storage Temperature

Maximum: 49 °C (120.2 °F)

Storage Conditions

Containers should be tightly closed to prevent contamination with foreign materials and moisture.

Substances to Avoid

None known.

8. Exposure Controls/Personal Protection

Exposure Limits

Any component which is listed in section 3 and is not listed in this section does not have a known ACGIH TLV, OSHA PEL, or supplier recommended occupational exposure limit.

Industrial Hygiene/Ventilation Measures

General dilution and local exhaust as necessary to control airborne vapors, mists, dusts, and thermal decomposition products below appropriate airborne concentration standards/guidelines, especially during cutting, grinding, and high heat operations.

Respiratory Protection

Although no exposure limit has been established for this product, the OSHA PEL for Particulates Not Otherwise Regulated (PNOR) of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction is recommended. In addition, the ACGIH recommends 3 mg/m3 - respirable particles and 10 mg/m3 - inhalable particles for Particles (insoluble or poorly soluble) Not Otherwise Specified (PNOS). In the event that these limits are exceeded, an air-purifying respirator (APR) equipped with particulate (P100) cartridges is recommended.

Hand Protection

Ensure gloves remain in good condition during use and replace if any deterioration is observed. Wear heat-resistant gloves when handling molten material.

Eye Protection

Safety glasses with side-shields

Skin Protection

No special skin protection requirements during normal handling and use.

Additional Protective Measures

Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product. Purgings should be collected as small flat thin shapes or thin strands to allow for rapid cooling.

9. Physical and Chemical Properties

State of Matter Solid
Appearance Pellets
Color Natural
Odor Odorless
Melting Point 220 °C (428 °F)
Flash Point 320 °C (608 °F)
Density ca. 1.1 - 1.2 g/cm3 (DIN 53479)
Solubility in Water Practically insoluble
Auto-ignition Temperature > 320 °C (> 608 °F)
Decomposition Temperature >= 380 °C (716 °F)
Softening Point 100 - 200 °C (212 - 392 °F)
Bulk Density 600 - 700 kg/m3

10. Stability and Reactivity

Hazardous Reactions

Hazardous polymerization does not occur.

Stability

Stable

Materials to Avoid

None known.

Conditions to Avoid

Generation of dust clouds.

Hazardous Decomposition Products

By Fire and Thermal Decomposition: Phenol; Styrene; Acrylonitrile; Carbon oxides, Hazardous decomposition products due to incomplete combustion

11. Toxicological Information

Likely Routes of Exposure

Inhalation, Skin Contact, Eye Contact

Health Effects and Symptoms

Acute: Contact with heated material can cause thermal burns. Gases and fumes evolved during the thermal processing or decomposition of this material may irritate the eyes, skin, or respiratory tract.

Toxicity Data for: BAYBLEND T45PG 000000

No data available for this product.

Carcinogenicity

No carcinogenic substances as defined by IARC, NTP and/or OSHA

12. Ecological Information

Ecological Data for: BAYBLEND T45PG 000000

No data available for this product.

13. Disposal Considerations

Waste Disposal Method

Waste disposal should be in accordance with existing federal, state and local environmental control laws.

14. Transportation Information

Land transport (DOT)

Non-Regulated

Sea transport (IMDG)

Non-Regulated

Air transport (ICAO/IATA)

Non-Regulated

15. Regulatory Information

United States Federal Regulations

US. Toxic Substances Control Act: Listed on the Active Portion of the TSCA Inventory.

No substances are subject to TSCA 12(b) export notification requirements.

US. EPA CERCLA Hazardous Substances (40 CFR 302) Components

None

SARA Section 311/312 Hazard Categories

Refer to hazard classification information in Section 2.

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A) Components

None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required Components

None

US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261)

Under RCRA, it is the responsibility of the person who generates a solid waste, as defined in 40 CFR 261.2, to determine if that waste is a hazardous waste.

State Right-To-Know Information

The following chemicals are specifically listed by individual states; other product-specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

State Substance CAS-No. Concentration
Massachusetts, New Jersey, Pennsylvania Polymer CAS# is a trade secret >=1%
Massachusetts, New Jersey, Pennsylvania Bisphenol A Polycarbonate 25971-63-5 >=1%
Massachusetts Methylene Chloride 75-09-2 <=3 ppm
Massachusetts Acrylonitrile 107-13-1 <=100 ppm
California Proposition 65 List Acrylonitrile 107-13-1 <=100 ppm
California Proposition 65 List 1,3-Butadiene 106-99-0 <1 ppt
California Proposition 65 List Methylene Chloride 75-09-2 <=3 ppm
California Proposition 65 List Bisphenol A 80-05-7 Trace element
California Proposition 65 List Styrene 100-42-5 <0.1%

16. Other Information

The method of hazard communication for Covestro LLC is comprised of product labels and safety data sheets. Safety data sheets for all of our products and general product declarations are available for download at www.productsafetyfirst.covestro.com.

Contact: Product Safety Department

Telephone: (412) 413-2835

SDS Number: 112000010508

Version Date: 12/18/2018

SDS Version: 2.7

Information contained in this SDS is believed to be accurate but is furnished without warranty, express or implied, including warranties of merchantability or fitness for a particular purpose. The information relates only to the specific material designated herein. Covestro LLC assumes no legal responsibility for use of or reliance upon the information in this SDS and such information shall in no case be considered a part of our terms and conditions of sale. The user is responsible for determining whether the Covestro product is suitable for user’s method of use or application. Covestro is not liable for any failure to observe the precautionary measures described in this SDS or for any misuse of the product.

Changes since the last version are highlighted in the margin. This version replaces all previous versions.



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